The synthesis and evaluation of new α-hydrogen nitroxides for 'living' free radical polymerization

Rebecca Braslau, Greg O'Bryan, Aaron Nilsen, Jeff Henise, Thanchanok Thongpaisanwong, Erin Murphy, Laura Mueller, Jean Ruehl

Research output: Contribution to journalArticle

25 Scopus citations

Abstract

Three N-alkoxyamines were synthesized for use in nitroxide-mediated radical polymerization. Upon thermolysis, they generate new acyclic α-hydrogen nitroxides: one adamantyl substituted and two diol-containing nitroxides. The initiators were tested in polymerization reactions in direct comparison with the initiator derived from the nitroxide TIPNO.

Original languageEnglish (US)
Pages (from-to)1496-1506
Number of pages11
JournalSynthesis
Issue number9
DOIs
StatePublished - Jun 6 2005

Keywords

  • Free radicals
  • Grignard reaction
  • Nitrone
  • Nitroxide
  • Polymers

ASJC Scopus subject areas

  • Catalysis
  • Organic Chemistry

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    Braslau, R., O'Bryan, G., Nilsen, A., Henise, J., Thongpaisanwong, T., Murphy, E., Mueller, L., & Ruehl, J. (2005). The synthesis and evaluation of new α-hydrogen nitroxides for 'living' free radical polymerization. Synthesis, (9), 1496-1506. https://doi.org/10.1055/s-2005-869894