Synthesis, crystal structure, and conversion of the polycyclic tris-anhydrotetramer of O-aminobenzaldehyde to Cu(TAAB)2+

Xiangshu Xiao, Phillip E. Fanwick, Mark Cushman

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Polycyclic tris-anhydrotetramer 6 of o-aminobenzaldehyde was synthesized directly from reduction of o-nitrobenzaldehyde and its structure was determined by X-ray crystallography. This provides a practical synthesis of 6, as opposed to starting from the unstable o-aminobenzaldehyde. The tris-anhydrotetramer 6 is useful for the synthesis of a variety of TAAB-metal complexes.

Original languageEnglish (US)
Pages (from-to)3901-3907
Number of pages7
JournalSynthetic Communications
Volume34
Issue number21
DOIs
StatePublished - 2004
Externally publishedYes

Fingerprint

2-nitrobenzaldehyde
Crystal structure
X ray crystallography
Coordination Complexes
copper tetrabenzo(b,f,j,n)-1,5,9,13-tetraazacyclohexadecine

Keywords

  • Biological activities
  • o-Aminobenzaldehyde
  • o-Nitrobenzaldehyde
  • Polycyclic tris-anhydrotetramer
  • Reduction
  • TAAB
  • X-ray

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Synthesis, crystal structure, and conversion of the polycyclic tris-anhydrotetramer of O-aminobenzaldehyde to Cu(TAAB)2+. / Xiao, Xiangshu; Fanwick, Phillip E.; Cushman, Mark.

In: Synthetic Communications, Vol. 34, No. 21, 2004, p. 3901-3907.

Research output: Contribution to journalArticle

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AU - Fanwick, Phillip E.

AU - Cushman, Mark

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KW - X-ray

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