Synthesis, crystal structure, and conversion of the polycyclic tris-anhydrotetramer of O-aminobenzaldehyde to Cu(TAAB)2+

Xiangshu Xiao; Phillip E. Fanwick; Mark Cushman

doi:10.1081/SCC-200034780

Synthesis, crystal structure, and conversion of the polycyclic tris-anhydrotetramer of O-aminobenzaldehyde to Cu(TAAB)²⁺

Xiangshu Xiao, Phillip E. Fanwick, Mark Cushman

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

Polycyclic tris-anhydrotetramer 6 of o-aminobenzaldehyde was synthesized directly from reduction of o-nitrobenzaldehyde and its structure was determined by X-ray crystallography. This provides a practical synthesis of 6, as opposed to starting from the unstable o-aminobenzaldehyde. The tris-anhydrotetramer 6 is useful for the synthesis of a variety of TAAB-metal complexes.

Original language	English (US)
Pages (from-to)	3901-3907
Number of pages	7
Journal	Synthetic Communications
Volume	34
Issue number	21
DOIs	https://doi.org/10.1081/SCC-200034780
State	Published - 2004
Externally published	Yes

Keywords

Biological activities
Polycyclic tris-anhydrotetramer
Reduction
TAAB
X-ray
o-Aminobenzaldehyde
o-Nitrobenzaldehyde

ASJC Scopus subject areas

Organic Chemistry

Access to Document

10.1081/SCC-200034780

Cite this

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title = "Synthesis, crystal structure, and conversion of the polycyclic tris-anhydrotetramer of O-aminobenzaldehyde to Cu(TAAB)2+",

abstract = "Polycyclic tris-anhydrotetramer 6 of o-aminobenzaldehyde was synthesized directly from reduction of o-nitrobenzaldehyde and its structure was determined by X-ray crystallography. This provides a practical synthesis of 6, as opposed to starting from the unstable o-aminobenzaldehyde. The tris-anhydrotetramer 6 is useful for the synthesis of a variety of TAAB-metal complexes.",

keywords = "Biological activities, Polycyclic tris-anhydrotetramer, Reduction, TAAB, X-ray, o-Aminobenzaldehyde, o-Nitrobenzaldehyde",

author = "Xiangshu Xiao and Fanwick, {Phillip E.} and Mark Cushman",

note = "Funding Information: This work was made possible by the National Institutes of Health (NIH) through support of this work with Research Grant UO1 CA89566.",

year = "2004",

doi = "10.1081/SCC-200034780",

language = "English (US)",

volume = "34",

pages = "3901--3907",

journal = "Synthetic Communications",

issn = "0039-7911",

publisher = "Taylor and Francis Ltd.",

number = "21",

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TY - JOUR

T1 - Synthesis, crystal structure, and conversion of the polycyclic tris-anhydrotetramer of O-aminobenzaldehyde to Cu(TAAB)2+

AU - Xiao, Xiangshu

AU - Fanwick, Phillip E.

AU - Cushman, Mark

N1 - Funding Information: This work was made possible by the National Institutes of Health (NIH) through support of this work with Research Grant UO1 CA89566.

PY - 2004

Y1 - 2004

N2 - Polycyclic tris-anhydrotetramer 6 of o-aminobenzaldehyde was synthesized directly from reduction of o-nitrobenzaldehyde and its structure was determined by X-ray crystallography. This provides a practical synthesis of 6, as opposed to starting from the unstable o-aminobenzaldehyde. The tris-anhydrotetramer 6 is useful for the synthesis of a variety of TAAB-metal complexes.

AB - Polycyclic tris-anhydrotetramer 6 of o-aminobenzaldehyde was synthesized directly from reduction of o-nitrobenzaldehyde and its structure was determined by X-ray crystallography. This provides a practical synthesis of 6, as opposed to starting from the unstable o-aminobenzaldehyde. The tris-anhydrotetramer 6 is useful for the synthesis of a variety of TAAB-metal complexes.

KW - Biological activities

KW - Polycyclic tris-anhydrotetramer

KW - Reduction

KW - TAAB

KW - X-ray

KW - o-Aminobenzaldehyde

KW - o-Nitrobenzaldehyde

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U2 - 10.1081/SCC-200034780

DO - 10.1081/SCC-200034780

M3 - Article

AN - SCOPUS:7644236853

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VL - 34

SP - 3901

EP - 3907

JO - Synthetic Communications

JF - Synthetic Communications

IS - 21

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