Stereoelectronic Control of Electron Transfer In the Oxidative Addition of [py(dmgH)2CoI]Na+ to Carbohydrate Secondary Iodides

Bruce P. Branchaud, Gui Xue Yu

Research output: Contribution to journalArticle

8 Scopus citations

Abstract

The relative rates of oxidative addition of secondary carbohydrate iodides 2, 5, and 7 with [py-(dmgHJjCoI], to form mixtures of diastereomeric alkyl cobaloximes 3 and 8, are consistent with steric inhibition of the electron-transfer step. On the basis of these and previously reported observations, a unified mechanism for oxidative addition is proposed.

Original languageEnglish (US)
Pages (from-to)3795-3797
Number of pages3
JournalOrganometallics
Volume10
Issue number11
DOIs
StatePublished - Nov 1 1991

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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