Role of the five-coordinate intermediate in the stereochemistry of dissociative reactions of octahedral compounds

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Abstract

Compound topological graphs have been presented which allow the systematic analysis of the stereochemical aspects of any substitution or stereoisomerization reaction of an octahedral six-coordinate compound which proceeds via a five-coordinate intermediate capable of rearranging according to the Berry pseudorotation mechanism. Examples are given of a substitution reaction of a complex with monodentate ligands and intramolecular isomerization reactions of tris bidentate chelates.

Original languageEnglish (US)
Pages (from-to)1459-1467
Number of pages9
JournalJournal of the American Chemical Society
Volume95
Issue number5
StatePublished - 1973
Externally publishedYes

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Stereochemistry
Fruit
Substitution reactions
Ligands
Isomerization

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

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abstract = "Compound topological graphs have been presented which allow the systematic analysis of the stereochemical aspects of any substitution or stereoisomerization reaction of an octahedral six-coordinate compound which proceeds via a five-coordinate intermediate capable of rearranging according to the Berry pseudorotation mechanism. Examples are given of a substitution reaction of a complex with monodentate ligands and intramolecular isomerization reactions of tris bidentate chelates.",
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AB - Compound topological graphs have been presented which allow the systematic analysis of the stereochemical aspects of any substitution or stereoisomerization reaction of an octahedral six-coordinate compound which proceeds via a five-coordinate intermediate capable of rearranging according to the Berry pseudorotation mechanism. Examples are given of a substitution reaction of a complex with monodentate ligands and intramolecular isomerization reactions of tris bidentate chelates.

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