Friedel-crafts acylation reactions in pyridinium based ionic liquids

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56 Scopus citations

Abstract

The Friedel-Crafts acylations of representative aromatic compounds with acetic anhydride in pyridinium based ionic liquids (ILs) were investigated. The effect of factors such as reactant composition, catalyst-IL composition, catalyst dosage and reaction temperature were studied. The reactions were found to proceed under relatively mild conditions with excellent conversions; and a simple product isolation procedure was achieved. ILs could also be recycled and reused effectively, thus rendering green characteristic to this reaction.

Original languageEnglish (US)
Pages (from-to)3609-3613
Number of pages5
JournalJournal of Organometallic Chemistry
Volume690
Issue number15
DOIs
StatePublished - Aug 1 2005
Externally publishedYes

Keywords

  • Friedel-Crafts acylation
  • Pyridinium ionic liquid

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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