Electrochemical switch based on the photoisomerization of a diarylethene derivative

Nan Xie, De X. Zeng, Yi Chen

Research output: Contribution to journalArticle

11 Scopus citations

Abstract

3,4-Bis[5-(2′-thiophene)-2-methylthien-3-yl]-2,5-dihydrothiophene 1a was synthesized and underwent excellent ring-opening and ring-closing photoisomerization in solution with UV/Vis light irradiation. Both ring-open isomer and ring-closed isomer of diarylethene showed electrochemical behavior, and the oxidation/reduction potential was reversible based on the ring-opening and ring-closing photoisomerization of diarylethene with UV/Vis light irradiation. Besides, a combination of photochromism and electrochromism of 1a was also observed.

Original languageEnglish (US)
Pages (from-to)27-30
Number of pages4
JournalJournal of Electroanalytical Chemistry
Volume609
Issue number1
DOIs
StatePublished - Oct 15 2007

Keywords

  • Diarylethene
  • Electrochemical switch
  • Electrochromism
  • Photochromism
  • Photoisomerization

ASJC Scopus subject areas

  • Analytical Chemistry
  • Chemical Engineering(all)
  • Electrochemistry

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