Cobaloxime-Mcdiated Radical Alkyl-Heteroaromatic Substitution

Bruce P. Branchaud, Youngshin Lee Choi

Research output: Contribution to journalArticle

19 Scopus citations

Abstract

The first examples of cobaloxime-mediated radical alkyl-heteroaromatic cross-coupling, replacing a C-H in the protonated heteroaromatic with a C-alkyl, are accomplished via anaerobic visible light photolysis of 95% EtOH solutions of primary and secondary alkyl cobaloximes, RCoIII(dmgH)2py (dmgH = dimethylglyoxime monoanion), and pyridinium, quinolinium, 4-methylpyridinium, benzothiazolium, and benzimidazolium ptoluenesulfonate.

Original languageEnglish (US)
Pages (from-to)4638-4641
Number of pages4
JournalJournal of Organic Chemistry
Volume53
Issue number19
DOIs
StatePublished - Sep 1 1988

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ASJC Scopus subject areas

  • Organic Chemistry

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