Bis[2,3-butanedione dioximato(1-)-N,N′]-(pyridine){[(R)-5,6,7,8-tetrahydro-8-indolizinyl] methyl}cobalt(III)

Jennifer L. Gage; Timothy J.R. Weakley; Bruce P. Branchaud

doi:10.1107/S0108270197012663

Bis[2,3-butanedione dioximato(1-)-N,N′]-(pyridine){[(R)-5,6,7,8-tetrahydro-8-indolizinyl] methyl}cobalt(III)

Jennifer L. Gage, Timothy J.R. Weakley, Bruce P. Branchaud

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound, [Co(C₉H₁₂N)(C₄H₇N₂O ₂)₂(C₅H₅-N)], has the expected structure with the C-bonded heterocyclic ligand trans to pyridine. The Co-C bond lengths in the two independent molecules [2.032(5) and 2.009 (6) Å] are near the lower end of the range found for related compounds and do not account for the observed thermal instability.

Original language	English (US)
Pages (from-to)	22-24
Number of pages	3
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	54
Issue number	1
DOIs	https://doi.org/10.1107/S0108270197012663
State	Published - 1998
Externally published	Yes

ASJC Scopus subject areas

General Biochemistry, Genetics and Molecular Biology

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title = "Bis[2,3-butanedione dioximato(1-)-N,N′]-(pyridine){[(R)-5,6,7,8-tetrahydro-8-indolizinyl] methyl}cobalt(III)",

abstract = "The title compound, [Co(C9H12N)(C4H7N2O 2)2(C5H5-N)], has the expected structure with the C-bonded heterocyclic ligand trans to pyridine. The Co-C bond lengths in the two independent molecules [2.032(5) and 2.009 (6) {\AA}] are near the lower end of the range found for related compounds and do not account for the observed thermal instability.",

author = "Gage, {Jennifer L.} and Weakley, {Timothy J.R.} and Branchaud, {Bruce P.}",

year = "1998",

doi = "10.1107/S0108270197012663",

language = "English (US)",

volume = "54",

pages = "22--24",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "1",

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TY - JOUR

T1 - Bis[2,3-butanedione dioximato(1-)-N,N′]-(pyridine){[(R)-5,6,7,8-tetrahydro-8-indolizinyl] methyl}cobalt(III)

AU - Gage, Jennifer L.

AU - Weakley, Timothy J.R.

AU - Branchaud, Bruce P.

PY - 1998

Y1 - 1998

N2 - The title compound, [Co(C9H12N)(C4H7N2O 2)2(C5H5-N)], has the expected structure with the C-bonded heterocyclic ligand trans to pyridine. The Co-C bond lengths in the two independent molecules [2.032(5) and 2.009 (6) Å] are near the lower end of the range found for related compounds and do not account for the observed thermal instability.

AB - The title compound, [Co(C9H12N)(C4H7N2O 2)2(C5H5-N)], has the expected structure with the C-bonded heterocyclic ligand trans to pyridine. The Co-C bond lengths in the two independent molecules [2.032(5) and 2.009 (6) Å] are near the lower end of the range found for related compounds and do not account for the observed thermal instability.

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U2 - 10.1107/S0108270197012663

DO - 10.1107/S0108270197012663

M3 - Article

AN - SCOPUS:0031646927

SN - 0108-2701

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EP - 24

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 1

ER -

Bis[2,3-butanedione dioximato(1-)-N,N′]-(pyridine){[(R)-5,6,7,8-tetrahydro-8-indolizinyl] methyl}cobalt(III)

Abstract

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