Bis[2,3-butanedione dioximato(1-)-N,N′]-(pyridine){[(R)-5,6,7,8-tetrahydro-8-indolizinyl] methyl}cobalt(III)

Jennifer L. Gage, Timothy J.R. Weakley, Bruce Branchaud

Research output: Contribution to journalArticle

Abstract

The title compound, [Co(C9H12N)(C4H7N2O 2)2(C5H5-N)], has the expected structure with the C-bonded heterocyclic ligand trans to pyridine. The Co-C bond lengths in the two independent molecules [2.032(5) and 2.009 (6) Å] are near the lower end of the range found for related compounds and do not account for the observed thermal instability.

Original languageEnglish (US)
Pages (from-to)22-24
Number of pages3
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume54
Issue number1
DOIs
StatePublished - Jan 1 1998
Externally publishedYes

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Diacetyl
Bond length
Cobalt
Hot Temperature
Ligands
Molecules
pyridine

ASJC Scopus subject areas

  • Biochemistry, Genetics and Molecular Biology(all)

Cite this

Bis[2,3-butanedione dioximato(1-)-N,N′]-(pyridine){[(R)-5,6,7,8-tetrahydro-8-indolizinyl] methyl}cobalt(III). / Gage, Jennifer L.; Weakley, Timothy J.R.; Branchaud, Bruce.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 54, No. 1, 01.01.1998, p. 22-24.

Research output: Contribution to journalArticle

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abstract = "The title compound, [Co(C9H12N)(C4H7N2O 2)2(C5H5-N)], has the expected structure with the C-bonded heterocyclic ligand trans to pyridine. The Co-C bond lengths in the two independent molecules [2.032(5) and 2.009 (6) {\AA}] are near the lower end of the range found for related compounds and do not account for the observed thermal instability.",
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AU - Branchaud, Bruce

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AB - The title compound, [Co(C9H12N)(C4H7N2O 2)2(C5H5-N)], has the expected structure with the C-bonded heterocyclic ligand trans to pyridine. The Co-C bond lengths in the two independent molecules [2.032(5) and 2.009 (6) Å] are near the lower end of the range found for related compounds and do not account for the observed thermal instability.

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