Traditionally, graphene quantum dots are prepared by fragmentation of graphene sheets into the nanoscale particles of controlled sizes followed by band gap adjustment by doping with electron-donating elements. Our novel synthetic aqueous arc discharge process has been developed to produce the blue-luminescent graphene quantum dots (bGQDs). The resulting bGQDs are ∼15 nm in diameter and the amount of oxygen-including functional groups can be controlled to 27.4% and 30.8% at 1 and 4 A of a current level, respectively. The presence of a band gap is confirmed by using scanning tunneling microscopy/spectroscopy (STM/STS). Additionally, we investigated the effect of oxygen doping levels on the band gap by photoluminescence (PL) behaviors and a density functional theory (DFT). The PL emission is red-shifted from 397 to 425 nm corresponding to the amount of oxygen-including functional groups in bGQDs and the DFT calculation confirms the decrease in a band gap from ∼2.0 to ∼1.7 eV due to electron donation from oxygen. In addition, our quantum dots have promising applications for practical use in optoelectronics devices. For example, tris-dibenzoylmethane mono-1,10-phenanthroline-europium (III) (EuIIIDP) is incorporated with bGQDs for white-light emission and is shown to be successfully fabricated into light-emitting polymer films.
ASJC Scopus subject areas
- Materials Science(all)