Thioether-ligated iron(ii) and iron(iii)-hydroperoxo/alkylperoxo complexes with an H-bond donor in the second coordination sphere

Leland R. Widger, Yunbo Jiang, Alison C. McQuilken, Tzuhsiung Yang, Maxime A. Siegler, Hirotoshi Matsumura, Pierre Moënne-Loccoz, Devesh Kumar, Sam P. De Visser, David P. Goldberg

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17 Scopus citations

Abstract

The non-heme iron complexes, [FeII(N3PySR)(CH 3CN)](BF4)2 (1) and [FeII(N3Py amideSR)](BF4)2 (2), afford rare examples of metastable Fe(iii)-OOH and Fe(iii)-OOtBu complexes containing equatorial thioether ligands and a single H-bond donor in the second coordination sphere. These peroxo complexes were characterized by a range of spectroscopic methods and density functional theory studies. The influence of a thioether ligand and of one H-bond donor on the stability and spectroscopic properties of these complexes was investigated. This journal is

Original languageEnglish (US)
Pages (from-to)7522-7532
Number of pages11
JournalDalton Transactions
Volume43
Issue number20
DOIs
StatePublished - May 28 2014

ASJC Scopus subject areas

  • Inorganic Chemistry

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    Widger, L. R., Jiang, Y., McQuilken, A. C., Yang, T., Siegler, M. A., Matsumura, H., Moënne-Loccoz, P., Kumar, D., De Visser, S. P., & Goldberg, D. P. (2014). Thioether-ligated iron(ii) and iron(iii)-hydroperoxo/alkylperoxo complexes with an H-bond donor in the second coordination sphere. Dalton Transactions, 43(20), 7522-7532. https://doi.org/10.1039/c4dt00281d