Thioether-ligated iron(ii) and iron(iii)-hydroperoxo/alkylperoxo complexes with an H-bond donor in the second coordination sphere

Leland R. Widger, Yunbo Jiang, Alison C. McQuilken, Tzuhsiung Yang, Maxime A. Siegler, Hirotoshi Matsumura, Pierre Moenne-Loccoz, Devesh Kumar, Sam P. De Visser, David P. Goldberg

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Abstract

The non-heme iron complexes, [FeII(N3PySR)(CH 3CN)](BF4)2 (1) and [FeII(N3Py amideSR)](BF4)2 (2), afford rare examples of metastable Fe(iii)-OOH and Fe(iii)-OOtBu complexes containing equatorial thioether ligands and a single H-bond donor in the second coordination sphere. These peroxo complexes were characterized by a range of spectroscopic methods and density functional theory studies. The influence of a thioether ligand and of one H-bond donor on the stability and spectroscopic properties of these complexes was investigated. This journal is

Original languageEnglish (US)
Pages (from-to)7522-7532
Number of pages11
JournalDalton Transactions
Volume43
Issue number20
DOIs
StatePublished - May 28 2014

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Sulfides
Iron
Ligands
Density functional theory

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

Widger, L. R., Jiang, Y., McQuilken, A. C., Yang, T., Siegler, M. A., Matsumura, H., ... Goldberg, D. P. (2014). Thioether-ligated iron(ii) and iron(iii)-hydroperoxo/alkylperoxo complexes with an H-bond donor in the second coordination sphere. Dalton Transactions, 43(20), 7522-7532. https://doi.org/10.1039/c4dt00281d

Thioether-ligated iron(ii) and iron(iii)-hydroperoxo/alkylperoxo complexes with an H-bond donor in the second coordination sphere. / Widger, Leland R.; Jiang, Yunbo; McQuilken, Alison C.; Yang, Tzuhsiung; Siegler, Maxime A.; Matsumura, Hirotoshi; Moenne-Loccoz, Pierre; Kumar, Devesh; De Visser, Sam P.; Goldberg, David P.

In: Dalton Transactions, Vol. 43, No. 20, 28.05.2014, p. 7522-7532.

Research output: Contribution to journalArticle

Widger, LR, Jiang, Y, McQuilken, AC, Yang, T, Siegler, MA, Matsumura, H, Moenne-Loccoz, P, Kumar, D, De Visser, SP & Goldberg, DP 2014, 'Thioether-ligated iron(ii) and iron(iii)-hydroperoxo/alkylperoxo complexes with an H-bond donor in the second coordination sphere', Dalton Transactions, vol. 43, no. 20, pp. 7522-7532. https://doi.org/10.1039/c4dt00281d
Widger, Leland R. ; Jiang, Yunbo ; McQuilken, Alison C. ; Yang, Tzuhsiung ; Siegler, Maxime A. ; Matsumura, Hirotoshi ; Moenne-Loccoz, Pierre ; Kumar, Devesh ; De Visser, Sam P. ; Goldberg, David P. / Thioether-ligated iron(ii) and iron(iii)-hydroperoxo/alkylperoxo complexes with an H-bond donor in the second coordination sphere. In: Dalton Transactions. 2014 ; Vol. 43, No. 20. pp. 7522-7532.
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