Abstract
The non-heme iron complexes, [FeII(N3PySR)(CH 3CN)](BF4)2 (1) and [FeII(N3Py amideSR)](BF4)2 (2), afford rare examples of metastable Fe(iii)-OOH and Fe(iii)-OOtBu complexes containing equatorial thioether ligands and a single H-bond donor in the second coordination sphere. These peroxo complexes were characterized by a range of spectroscopic methods and density functional theory studies. The influence of a thioether ligand and of one H-bond donor on the stability and spectroscopic properties of these complexes was investigated. This journal is
Original language | English (US) |
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Pages (from-to) | 7522-7532 |
Number of pages | 11 |
Journal | Dalton Transactions |
Volume | 43 |
Issue number | 20 |
DOIs | |
State | Published - May 28 2014 |
ASJC Scopus subject areas
- Inorganic Chemistry