Synthesis of nanoporous iminodiacetic acid sorbents for binding transition metals

Brad Busche, Robert Wiacek, Joseph Davidson, View Koonsiripaiboon, Wassana Yantasee, R. Shane Addleman, Glen E. Fryxell

Research output: Contribution to journalArticlepeer-review

27 Scopus citations

Abstract

Iminodiacetic acid (IDAA) forms strong complexes with a wide variety of metal ions. Using self-assembled monolayers in mesoporous supports (SAMMS) to present the IDAA ligand potentially allows for multiple metal-ligand interactions to enhance the metal binding affinity relative to that of randomly oriented polymer-based supports. This manuscript describes the synthesis of a novel nanostructured sorbent material built using self-assembly of a IDAA ligand inside a nanoporous silica, and demonstrates its use for capturing transition metal cations, and anionic metal complexes, such as PdCl4- 2.

Original languageEnglish (US)
Pages (from-to)312-315
Number of pages4
JournalInorganic Chemistry Communications
Volume12
Issue number4
DOIs
StatePublished - Apr 2009

Keywords

  • Chelation
  • Ion chromatography
  • Ion exchange
  • Nanoporous
  • Self-assembled monolayer
  • Sorbent

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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