Synthesis of allyl sulfides via a palladium mediated allylation

Barry M. Trost, Thomas (Tom) Scanlan

Research output: Contribution to journalArticle

69 Citations (Scopus)

Abstract

A mild chemo-, regio-, and diastereoselective substitution of allyl carbonates and vinyl epoxides by sulfur nucleophiles catalyzed by palladium can overcome difficulties in and complement conventional displacement without poisoning of the catalyst.

Original languageEnglish (US)
Pages (from-to)4141-4144
Number of pages4
JournalTetrahedron Letters
Volume27
Issue number35
DOIs
StatePublished - 1986
Externally publishedYes

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Allylation
Catalyst poisoning
Nucleophiles
Carbonates
Epoxy Compounds
Palladium
Sulfur
Poisoning
Substitution reactions
Catalysts
allyl sulfide

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

Synthesis of allyl sulfides via a palladium mediated allylation. / Trost, Barry M.; Scanlan, Thomas (Tom).

In: Tetrahedron Letters, Vol. 27, No. 35, 1986, p. 4141-4144.

Research output: Contribution to journalArticle

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