TY - JOUR
T1 - Reversed-phase high-performance liquid chromatography of C5 to C20 isoprenoid benzoates and naphthoates
AU - Yang, T. H.
AU - Zabriskie, T. M.
AU - Poulter, C. D.
PY - 1985
Y1 - 1985
N2 - Benzoate and naphthoate esters of C5 to C20 isoprenoid alcohols are excellent derivatives for reversed-phase liquid chromatography. Nonlinear responses of log k' to changes in the composition of the mobile phase are observed on Radial PAK C18 columns. In general, the capacity factors (k') increased with increases in carbon content and decreased with increases in the number of double bonds, branching, and Z double bond content. The large extinction coefficients of the aromatic ester moieties, especially the 2-naphthoates, provide high sensitivity for UV detection.
AB - Benzoate and naphthoate esters of C5 to C20 isoprenoid alcohols are excellent derivatives for reversed-phase liquid chromatography. Nonlinear responses of log k' to changes in the composition of the mobile phase are observed on Radial PAK C18 columns. In general, the capacity factors (k') increased with increases in carbon content and decreased with increases in the number of double bonds, branching, and Z double bond content. The large extinction coefficients of the aromatic ester moieties, especially the 2-naphthoates, provide high sensitivity for UV detection.
UR - http://www.scopus.com/inward/record.url?scp=0021891294&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0021891294&partnerID=8YFLogxK
U2 - 10.1016/s0076-6879(85)11013-x
DO - 10.1016/s0076-6879(85)11013-x
M3 - Article
C2 - 4033435
AN - SCOPUS:0021891294
SN - 0076-6879
VL - VOL. 111
SP - 252
EP - 263
JO - Methods in Enzymology
JF - Methods in Enzymology
ER -