Picture of a chelate in exchange: The crystal structure of NaHoDOTMA, a “semi”-hydrated chelate

Katherine M. Payne; Edward J. Valente; Silvio Aime; Mauro Botta; Mark Woods

doi:10.1039/c3cc38814j

Picture of a chelate in exchange: The crystal structure of NaHoDOTMA, a “semi”-hydrated chelate

Katherine M. Payne, Edward J. Valente, Silvio Aime, Mauro Botta, Mark Woods

Advanced Imaging Research Center

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

Crystallography generally only provides static structural information. This can render it an ineffective technique for probing dynamic solution state processes. A crystal of HoDOTMA affords unique structures that effectively represent that of a lanthanide tetra-acetate chelate mid-way through the water exchange process.

Original language	English (US)
Pages (from-to)	2320-2322
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	23
DOIs	https://doi.org/10.1039/c3cc38814j
State	Published - Feb 21 2013

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c3cc38814j

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title = "Picture of a chelate in exchange: The crystal structure of NaHoDOTMA, a “semi”-hydrated chelate",

abstract = "Crystallography generally only provides static structural information. This can render it an ineffective technique for probing dynamic solution state processes. A crystal of HoDOTMA affords unique structures that effectively represent that of a lanthanide tetra-acetate chelate mid-way through the water exchange process.",

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Picture of a chelate in exchange: The crystal structure of NaHoDOTMA, a “semi”-hydrated chelate

Abstract

ASJC Scopus subject areas

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