Neutralization of sulfuric acid aerosol by ammonia

James Huntzicker, R. A. Cary, C. S. Ling

Research output: Contribution to journalArticle

79 Citations (Scopus)

Abstract

The rate of neutralization of sulfuric acid aerosol by ammonia gas has been measured in a laboratory flow reactor for particle diameters between 0.3 and 1.4 μm and for relative humidities between 8 and 80%. The rates were between 21 and 70% of the rates expected if diffusion of NH3 to the aerosol droplets was the rate-determining factor, and the reaction coefficient, which is the fraction of gas-particle collisions resulting in a chemical reaction, increased with increasing particle size. A simple model of H2SO4 aerosol generation and neutralization in the atmosphere showed that sulfate aerosol more acidic than NH4 HSO should only be present during periods of rapid oxidation of the precursor SO2 and high ratios of [SO2] to [NH3] or when the equilibrium vapor pressure of NH3 over the partially neutralized H2SO4 droplet exceeds the ambient NH3 partial pressure.

Original languageEnglish (US)
Pages (from-to)819-824
Number of pages6
JournalEnvironmental Science and Technology
Volume14
Issue number7
DOIs
StatePublished - Jul 1980

Fingerprint

neutralization
Aerosols
Sulfuric acid
Ammonia
sulfuric acid
ammonia
aerosol
droplet
Gases
partial pressure
Vapor pressure
vapor pressure
gas
chemical reaction
Partial pressure
Sulfates
relative humidity
Chemical reactions
Atmospheric humidity
collision

ASJC Scopus subject areas

  • Environmental Engineering
  • Environmental Science(all)
  • Environmental Chemistry

Cite this

Neutralization of sulfuric acid aerosol by ammonia. / Huntzicker, James; Cary, R. A.; Ling, C. S.

In: Environmental Science and Technology, Vol. 14, No. 7, 07.1980, p. 819-824.

Research output: Contribution to journalArticle

Huntzicker, James ; Cary, R. A. ; Ling, C. S. / Neutralization of sulfuric acid aerosol by ammonia. In: Environmental Science and Technology. 1980 ; Vol. 14, No. 7. pp. 819-824.
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