Lateral injection of oxygen with the Bosporus plume-fingers of oxidizing potential in the Black Sea

Sergey K. Konovalov, George W. Luther, Gernot E. Friederich, Donald B. Nuzzio, Bradley Tebo, James W. Murray, Temel Oguz, Brian Glazer, Robert E. Trouwborst, Brian Clement, Karen J. Murray, Alexander S. Romanov

Research output: Contribution to journalArticle

95 Citations (Scopus)

Abstract

Saline and warm Mediterranean water flowing through the Bosporus Strait maintains a permanent pycnocline with vertical separation of oxic (O 2), suboxic (absence of O2 and H2S), and anoxic (H2S) zones in the Black Sea. The stable suboxic zone implies restricted vertical mixing of the upper oxic and lower anoxic layers and limited vertical flux of oxygen that cannot balance the upward flux of sulfide. We report data that directly confirm massive lateral injections (>200 km from the Bosporus) of oxygen-enriched waters of the Bosporus plume, created by the mixing of shallow, cold, intermediate-layer Black Sea water with Mediterranean water. These plume waters are laterally injected into the oxic layer and, more importantly, into the suboxic and anoxic layers over several small vertical scales ("fingers" of ∼5 m) at water densities (σt) from 15.0 to 16.4. O2 injection oxidizes Mn(II) to Mn(III,IV), which then oxidizes H2S. The onset of H2S detection occurs in deeper waters in the southwest (>170 m; σ t ≈ 16.4) relative to the west central Black Sea (110 m; σt ≈ 16.2) and coincides with increased MnO2 and S8 formation in the southwest.

Original languageEnglish (US)
Pages (from-to)2369-2376
Number of pages8
JournalLimnology and Oceanography
Volume48
Issue number6
StatePublished - Nov 2003
Externally publishedYes

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Black Sea
plume
injection
oxygen
Mediterranean Water
water
sulfides
pycnocline
vertical mixing
seawater
strait
deep water
sulfide

ASJC Scopus subject areas

  • Oceanography
  • Aquatic Science

Cite this

Konovalov, S. K., Luther, G. W., Friederich, G. E., Nuzzio, D. B., Tebo, B., Murray, J. W., ... Romanov, A. S. (2003). Lateral injection of oxygen with the Bosporus plume-fingers of oxidizing potential in the Black Sea. Limnology and Oceanography, 48(6), 2369-2376.

Lateral injection of oxygen with the Bosporus plume-fingers of oxidizing potential in the Black Sea. / Konovalov, Sergey K.; Luther, George W.; Friederich, Gernot E.; Nuzzio, Donald B.; Tebo, Bradley; Murray, James W.; Oguz, Temel; Glazer, Brian; Trouwborst, Robert E.; Clement, Brian; Murray, Karen J.; Romanov, Alexander S.

In: Limnology and Oceanography, Vol. 48, No. 6, 11.2003, p. 2369-2376.

Research output: Contribution to journalArticle

Konovalov, SK, Luther, GW, Friederich, GE, Nuzzio, DB, Tebo, B, Murray, JW, Oguz, T, Glazer, B, Trouwborst, RE, Clement, B, Murray, KJ & Romanov, AS 2003, 'Lateral injection of oxygen with the Bosporus plume-fingers of oxidizing potential in the Black Sea', Limnology and Oceanography, vol. 48, no. 6, pp. 2369-2376.
Konovalov SK, Luther GW, Friederich GE, Nuzzio DB, Tebo B, Murray JW et al. Lateral injection of oxygen with the Bosporus plume-fingers of oxidizing potential in the Black Sea. Limnology and Oceanography. 2003 Nov;48(6):2369-2376.
Konovalov, Sergey K. ; Luther, George W. ; Friederich, Gernot E. ; Nuzzio, Donald B. ; Tebo, Bradley ; Murray, James W. ; Oguz, Temel ; Glazer, Brian ; Trouwborst, Robert E. ; Clement, Brian ; Murray, Karen J. ; Romanov, Alexander S. / Lateral injection of oxygen with the Bosporus plume-fingers of oxidizing potential in the Black Sea. In: Limnology and Oceanography. 2003 ; Vol. 48, No. 6. pp. 2369-2376.
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AU - Nuzzio, Donald B.

AU - Tebo, Bradley

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AU - Oguz, Temel

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