Effect of co-initiator ratio on the polymer properties of experimental resin composites formulated with camphorquinone and phenyl-propanedione

Luis Felipe J Schneider, Larissa M. Cavalcante, Simonides Consani, Jack Ferracane

Research output: Contribution to journalArticle

50 Citations (Scopus)

Abstract

Objectives: To evaluate the effect of amine ratio (ethyl 4-dimethylaminobenzoate, EDMAB) on the maximum rate of polymerization (Rp max), degree of conversion (DC), Knoop hardness (KH), water sorption (Wsp), water solubility (Wsl) and color changes (ΔE) over time of resin composites formulated with the photoinitiators camphorquinone (CQ), phenylpropanedione (PPD) and CQ-PPD in combination. Materials and methods: Experimental resin composites were made with photoinitiator:amine ratios of 2:1, 1:1, 1:1.5 and 1:2 by weight. Rp max was evaluated with differential scanning calorimetry (DSC), DC with DSC and Fourier transformed infrared (FTIR) spectroscopy, KH with Knoop indentation, Wsp and Wsl adapted from ISO 4049; and color with a chromameter. The results were analyzed with two-way ANOVA/Tukey's multiple comparison test (p <0.05). Results: The higher the amine ratio in the composite, the higher was DC, Rp max, and KH, and the lower was Wsl, regardless of the photoinitiator type. The use of PPD alone resulted in poorer properties than CQ and CQ-PPD. Many factors seem to affect the color changes and the b-axis data revealed that the higher the amine ratio, the higher was the +b value (yellowing) for CQ and CQ-PPD formulations. Conclusions: Higher amine ratios led to improved polymer properties, but also produced more yellowing in resin composites with CQ and CQ-PPD. The use of PPD alone was not advantageous for producing good final properties when compared to CQ and CQ-PPD.

Original languageEnglish (US)
Pages (from-to)369-375
Number of pages7
JournalDental Materials
Volume25
Issue number3
DOIs
StatePublished - Mar 2009

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Composite Resins
Amines
Polymers
Resins
Composite materials
Solubility
Color
Sorption
Water
Differential scanning calorimetry
Hardness
Water hardness
Differential Scanning Calorimetry
Analysis of variance (ANOVA)
Indentation
Infrared spectroscopy
Polymerization
camphorquinone
Spectrum Analysis
Analysis of Variance

Keywords

  • Amine
  • Camphorquinone
  • Degree of conversion
  • Phenyl-propanedione
  • Polymerization
  • Resin composite

ASJC Scopus subject areas

  • Dentistry(all)
  • Materials Science(all)
  • Mechanics of Materials
  • Medicine(all)

Cite this

Effect of co-initiator ratio on the polymer properties of experimental resin composites formulated with camphorquinone and phenyl-propanedione. / Schneider, Luis Felipe J; Cavalcante, Larissa M.; Consani, Simonides; Ferracane, Jack.

In: Dental Materials, Vol. 25, No. 3, 03.2009, p. 369-375.

Research output: Contribution to journalArticle

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abstract = "Objectives: To evaluate the effect of amine ratio (ethyl 4-dimethylaminobenzoate, EDMAB) on the maximum rate of polymerization (Rp max), degree of conversion (DC), Knoop hardness (KH), water sorption (Wsp), water solubility (Wsl) and color changes (ΔE) over time of resin composites formulated with the photoinitiators camphorquinone (CQ), phenylpropanedione (PPD) and CQ-PPD in combination. Materials and methods: Experimental resin composites were made with photoinitiator:amine ratios of 2:1, 1:1, 1:1.5 and 1:2 by weight. Rp max was evaluated with differential scanning calorimetry (DSC), DC with DSC and Fourier transformed infrared (FTIR) spectroscopy, KH with Knoop indentation, Wsp and Wsl adapted from ISO 4049; and color with a chromameter. The results were analyzed with two-way ANOVA/Tukey's multiple comparison test (p <0.05). Results: The higher the amine ratio in the composite, the higher was DC, Rp max, and KH, and the lower was Wsl, regardless of the photoinitiator type. The use of PPD alone resulted in poorer properties than CQ and CQ-PPD. Many factors seem to affect the color changes and the b-axis data revealed that the higher the amine ratio, the higher was the +b value (yellowing) for CQ and CQ-PPD formulations. Conclusions: Higher amine ratios led to improved polymer properties, but also produced more yellowing in resin composites with CQ and CQ-PPD. The use of PPD alone was not advantageous for producing good final properties when compared to CQ and CQ-PPD.",
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T1 - Effect of co-initiator ratio on the polymer properties of experimental resin composites formulated with camphorquinone and phenyl-propanedione

AU - Schneider, Luis Felipe J

AU - Cavalcante, Larissa M.

AU - Consani, Simonides

AU - Ferracane, Jack

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N2 - Objectives: To evaluate the effect of amine ratio (ethyl 4-dimethylaminobenzoate, EDMAB) on the maximum rate of polymerization (Rp max), degree of conversion (DC), Knoop hardness (KH), water sorption (Wsp), water solubility (Wsl) and color changes (ΔE) over time of resin composites formulated with the photoinitiators camphorquinone (CQ), phenylpropanedione (PPD) and CQ-PPD in combination. Materials and methods: Experimental resin composites were made with photoinitiator:amine ratios of 2:1, 1:1, 1:1.5 and 1:2 by weight. Rp max was evaluated with differential scanning calorimetry (DSC), DC with DSC and Fourier transformed infrared (FTIR) spectroscopy, KH with Knoop indentation, Wsp and Wsl adapted from ISO 4049; and color with a chromameter. The results were analyzed with two-way ANOVA/Tukey's multiple comparison test (p <0.05). Results: The higher the amine ratio in the composite, the higher was DC, Rp max, and KH, and the lower was Wsl, regardless of the photoinitiator type. The use of PPD alone resulted in poorer properties than CQ and CQ-PPD. Many factors seem to affect the color changes and the b-axis data revealed that the higher the amine ratio, the higher was the +b value (yellowing) for CQ and CQ-PPD formulations. Conclusions: Higher amine ratios led to improved polymer properties, but also produced more yellowing in resin composites with CQ and CQ-PPD. The use of PPD alone was not advantageous for producing good final properties when compared to CQ and CQ-PPD.

AB - Objectives: To evaluate the effect of amine ratio (ethyl 4-dimethylaminobenzoate, EDMAB) on the maximum rate of polymerization (Rp max), degree of conversion (DC), Knoop hardness (KH), water sorption (Wsp), water solubility (Wsl) and color changes (ΔE) over time of resin composites formulated with the photoinitiators camphorquinone (CQ), phenylpropanedione (PPD) and CQ-PPD in combination. Materials and methods: Experimental resin composites were made with photoinitiator:amine ratios of 2:1, 1:1, 1:1.5 and 1:2 by weight. Rp max was evaluated with differential scanning calorimetry (DSC), DC with DSC and Fourier transformed infrared (FTIR) spectroscopy, KH with Knoop indentation, Wsp and Wsl adapted from ISO 4049; and color with a chromameter. The results were analyzed with two-way ANOVA/Tukey's multiple comparison test (p <0.05). Results: The higher the amine ratio in the composite, the higher was DC, Rp max, and KH, and the lower was Wsl, regardless of the photoinitiator type. The use of PPD alone resulted in poorer properties than CQ and CQ-PPD. Many factors seem to affect the color changes and the b-axis data revealed that the higher the amine ratio, the higher was the +b value (yellowing) for CQ and CQ-PPD formulations. Conclusions: Higher amine ratios led to improved polymer properties, but also produced more yellowing in resin composites with CQ and CQ-PPD. The use of PPD alone was not advantageous for producing good final properties when compared to CQ and CQ-PPD.

KW - Amine

KW - Camphorquinone

KW - Degree of conversion

KW - Phenyl-propanedione

KW - Polymerization

KW - Resin composite

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