Diffusion of volatile organic compounds in natural clay deposits

Laboratory tests

D. Myrand, R. W. Gillham, E. A. Sudicky, S. F. O'Hannesin, Richard Johnson

Research output: Contribution to journalArticle

60 Citations (Scopus)

Abstract

Diffusion coefficients for four volatile organic compounds of environmental concern, benzene, trichloroethylene, toluene and chlorobenzene, were measured on cores of saturated, unweathered glaciolacustrine clay obtained from boreholes at a hazardous waste disposal site near Sarnia, Ontario. The core material was transferred to stainless-steel cylinders constructed such that a closed solution reservoir was in contact with the upper surface of the core. The decline in concentration of the organic compounds in the reservoir was monitored over time and diffusion coefficients were determined by fitting a solution of the diffusion equation to the resulting data. The measured diffusion coefficients ranged from 0.3·10-7 to 1.1·10-7 cm2 s-1 for the four compounds, and were in reasonable agreement with values determined from concentration profiles in the clay material beneath the disposal pits. Diffusion coefficients were also calculated on the basis of distribution coefficients (Kd) determined from laboratory batch tests and from correlations with the organic carbon content of the clay material (foc). Values calculated on the basis of batch tests were substantially lower than the measured values, and those calculated on the basis of focc exceeded the measured values by almost an order of magnitude. The results indicate that reasonable estimates of diffusion coefficients for hydrophobic organic contaminants, for the purpose of predicting diffusive transport in natural fine-grained geologic materials can be obtained using the diffusion-cell procedure described in this paper. The poor estimate of the diffusion coefficients provided by the foc correlation procedure is consistent with significant sorption onto the mineral phase. Though not investigated, sample disturbance may have contributed to the low values calculated on the basis of batch Kd's.

Original languageEnglish (US)
Pages (from-to)159-177
Number of pages19
JournalJournal of Contaminant Hydrology
Volume10
Issue number2
DOIs
StatePublished - 1992

Fingerprint

Clay deposits
Volatile Organic Compounds
volatile organic compound
clay
Hazardous Waste
Trichloroethylene
chlorobenzene
laboratory test
Stainless Steel
Toluene
trichloroethylene
Organic carbon
Benzene
Boreholes
hazardous waste
Organic compounds
Waste disposal
waste disposal
toluene
Contacts (fluid mechanics)

ASJC Scopus subject areas

  • Environmental Chemistry
  • Water Science and Technology
  • Earth-Surface Processes
  • Environmental Science(all)
  • Earth and Planetary Sciences(all)

Cite this

Diffusion of volatile organic compounds in natural clay deposits : Laboratory tests. / Myrand, D.; Gillham, R. W.; Sudicky, E. A.; O'Hannesin, S. F.; Johnson, Richard.

In: Journal of Contaminant Hydrology, Vol. 10, No. 2, 1992, p. 159-177.

Research output: Contribution to journalArticle

Myrand, D. ; Gillham, R. W. ; Sudicky, E. A. ; O'Hannesin, S. F. ; Johnson, Richard. / Diffusion of volatile organic compounds in natural clay deposits : Laboratory tests. In: Journal of Contaminant Hydrology. 1992 ; Vol. 10, No. 2. pp. 159-177.
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