Cobaloxime-catalyzed radical alkyl-styryl cross couplings

Bruce P. Branchaud; William D. Detlefsen

doi:10.1016/0040-4039(91)80145-V

Cobaloxime-catalyzed radical alkyl-styryl cross couplings

Bruce P. Branchaud, William D. Detlefsen

Research output: Contribution to journal › Article › peer-review

60 Scopus citations

Abstract

Cobaloxime-catalyzed radical alkyl-styryl cross couplings can be accomplished by visible light photolysis of various alkyl bromide + styrene + in-situ-generated Co^II (dmgH)2py + Zn in refluxing CH₃CN or refluxing 95%EtOH.

Original language	English (US)
Pages (from-to)	6273-6276
Number of pages	4
Journal	Tetrahedron Letters
Volume	32
Issue number	44
DOIs	https://doi.org/10.1016/0040-4039(91)80145-V
State	Published - Oct 28 1991
Externally published	Yes

Keywords

catalytic cross couplings
cobaloximes
radical-alkene additions

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

Access to Document

10.1016/0040-4039(91)80145-V

Cite this

@article{2cc9ed7eaf6d4d9b86cc665c6050dbb8,

title = "Cobaloxime-catalyzed radical alkyl-styryl cross couplings",

abstract = "Cobaloxime-catalyzed radical alkyl-styryl cross couplings can be accomplished by visible light photolysis of various alkyl bromide + styrene + in-situ-generated CoII (dmgH)2py + Zn in refluxing CH3CN or refluxing 95%EtOH.",

keywords = "catalytic cross couplings, cobaloximes, radical-alkene additions",

author = "Branchaud, {Bruce P.} and Detlefsen, {William D.}",

note = "Funding Information: Acknowledgement. The National Science Foundation (CHE 8808605)p rovided financial support for this research. The Alfred P. Sloan Foundationp rovidedpartial supportf or the early stageso f this work.",

year = "1991",

month = oct,

day = "28",

doi = "10.1016/0040-4039(91)80145-V",

language = "English (US)",

volume = "32",

pages = "6273--6276",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Limited",

number = "44",

}

TY - JOUR

T1 - Cobaloxime-catalyzed radical alkyl-styryl cross couplings

AU - Branchaud, Bruce P.

AU - Detlefsen, William D.

N1 - Funding Information: Acknowledgement. The National Science Foundation (CHE 8808605)p rovided financial support for this research. The Alfred P. Sloan Foundationp rovidedpartial supportf or the early stageso f this work.

PY - 1991/10/28

Y1 - 1991/10/28

N2 - Cobaloxime-catalyzed radical alkyl-styryl cross couplings can be accomplished by visible light photolysis of various alkyl bromide + styrene + in-situ-generated CoII (dmgH)2py + Zn in refluxing CH3CN or refluxing 95%EtOH.

AB - Cobaloxime-catalyzed radical alkyl-styryl cross couplings can be accomplished by visible light photolysis of various alkyl bromide + styrene + in-situ-generated CoII (dmgH)2py + Zn in refluxing CH3CN or refluxing 95%EtOH.

KW - catalytic cross couplings

KW - cobaloximes

KW - radical-alkene additions

UR - http://www.scopus.com/inward/record.url?scp=0025939924&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0025939924&partnerID=8YFLogxK

U2 - 10.1016/0040-4039(91)80145-V

DO - 10.1016/0040-4039(91)80145-V

M3 - Article

AN - SCOPUS:0025939924

SN - 0040-4039

VL - 32

SP - 6273

EP - 6276

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 44

ER -

Cobaloxime-catalyzed radical alkyl-styryl cross couplings

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this