Application of chiral ionic liquids in the copper catalyzed enantioselective 1,4-addition of diethylzinc to enones

Sanjay V. Malhotra; Yun Wang

doi:10.1016/j.tetasy.2006.03.030

Application of chiral ionic liquids in the copper catalyzed enantioselective 1,4-addition of diethylzinc to enones

Sanjay V. Malhotra, Yun Wang

Research output: Contribution to journal › Article › peer-review

46 Scopus citations

Abstract

Copper catalyzed enantioselective addition of diethylzinc to various enones has been achieved in the presence of a new class of chiral ionic liquid (ChirILs) derived from α-pinene. This first study on the application of ChirILs for the title reaction shows that the chiral reaction medium has a significant influence on chiral induction.

Original language	English (US)
Pages (from-to)	1032-1035
Number of pages	4
Journal	Tetrahedron Asymmetry
Volume	17
Issue number	7
DOIs	https://doi.org/10.1016/j.tetasy.2006.03.030
State	Published - Apr 3 2006
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1016/j.tetasy.2006.03.030

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title = "Application of chiral ionic liquids in the copper catalyzed enantioselective 1,4-addition of diethylzinc to enones",

abstract = "Copper catalyzed enantioselective addition of diethylzinc to various enones has been achieved in the presence of a new class of chiral ionic liquid (ChirILs) derived from α-pinene. This first study on the application of ChirILs for the title reaction shows that the chiral reaction medium has a significant influence on chiral induction.",

author = "Malhotra, {Sanjay V.} and Yun Wang",

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AU - Wang, Yun

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Y1 - 2006/4/3

N2 - Copper catalyzed enantioselective addition of diethylzinc to various enones has been achieved in the presence of a new class of chiral ionic liquid (ChirILs) derived from α-pinene. This first study on the application of ChirILs for the title reaction shows that the chiral reaction medium has a significant influence on chiral induction.

AB - Copper catalyzed enantioselective addition of diethylzinc to various enones has been achieved in the presence of a new class of chiral ionic liquid (ChirILs) derived from α-pinene. This first study on the application of ChirILs for the title reaction shows that the chiral reaction medium has a significant influence on chiral induction.

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ER -

Application of chiral ionic liquids in the copper catalyzed enantioselective 1,4-addition of diethylzinc to enones

Abstract

ASJC Scopus subject areas

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