Anomalous 14N quadrupole coupling constant of methyl isocyanide in liquid crystals

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

The14N quadrupole coupling constant (QCC) for methyl isocyanide obtained from 1H and 14N N.M.R. measurements in liquid crystal solutions is reported as a function of temperature for two liquid crystal solvents. A marked linear temperature dependence is observed in both solvents. The measured QCC varies by 20 per cent over a 50°C range.

Original languageEnglish (US)
Pages (from-to)651-656
Number of pages6
JournalMolecular Physics
Volume54
Issue number3
DOIs
StatePublished - 1985
Externally publishedYes

Fingerprint

Liquid Crystals
quadrupoles
liquid crystals
Temperature
Nuclear magnetic resonance
temperature dependence
nuclear magnetic resonance
temperature
methylisonitrile
Proton Magnetic Resonance Spectroscopy

ASJC Scopus subject areas

  • Biophysics
  • Molecular Biology
  • Physical and Theoretical Chemistry
  • Condensed Matter Physics

Cite this

Anomalous 14N quadrupole coupling constant of methyl isocyanide in liquid crystals. / Barbara, Thomas.

In: Molecular Physics, Vol. 54, No. 3, 1985, p. 651-656.

Research output: Contribution to journalArticle

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abstract = "The14N quadrupole coupling constant (QCC) for methyl isocyanide obtained from 1H and 14N N.M.R. measurements in liquid crystal solutions is reported as a function of temperature for two liquid crystal solvents. A marked linear temperature dependence is observed in both solvents. The measured QCC varies by 20 per cent over a 50°C range.",
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