Anomalous 14N quadrupole coupling constant of methyl isocyanide in liquid crystals

Thomas M. Barbara

doi:10.1080/00268978500100501

Anomalous ¹⁴N quadrupole coupling constant of methyl isocyanide in liquid crystals

Thomas M. Barbara

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

The¹⁴N quadrupole coupling constant (QCC) for methyl isocyanide obtained from ¹H and ¹⁴N N.M.R. measurements in liquid crystal solutions is reported as a function of temperature for two liquid crystal solvents. A marked linear temperature dependence is observed in both solvents. The measured QCC varies by 20 per cent over a 50°C range.

Original language	English (US)
Pages (from-to)	651-656
Number of pages	6
Journal	Molecular Physics
Volume	54
Issue number	3
DOIs	https://doi.org/10.1080/00268978500100501
State	Published - 1985
Externally published	Yes

ASJC Scopus subject areas

Biophysics
Molecular Biology
Condensed Matter Physics
Physical and Theoretical Chemistry

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10.1080/00268978500100501

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title = "Anomalous 14N quadrupole coupling constant of methyl isocyanide in liquid crystals",

abstract = "The14N quadrupole coupling constant (QCC) for methyl isocyanide obtained from 1H and 14N N.M.R. measurements in liquid crystal solutions is reported as a function of temperature for two liquid crystal solvents. A marked linear temperature dependence is observed in both solvents. The measured QCC varies by 20 per cent over a 50°C range.",

author = "Barbara, {Thomas M.}",

note = "Funding Information: It is a pleasure to thank Professors R. L. and R. R. Vold for a NSF postdoctoral appointment under grant CHE 81-22097 and Dr. John Wright for technical assistance.",

year = "1985",

doi = "10.1080/00268978500100501",

language = "English (US)",

volume = "54",

pages = "651--656",

journal = "Molecular Physics",

issn = "0026-8976",

publisher = "Taylor and Francis Ltd.",

number = "3",

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T1 - Anomalous 14N quadrupole coupling constant of methyl isocyanide in liquid crystals

AU - Barbara, Thomas M.

N1 - Funding Information: It is a pleasure to thank Professors R. L. and R. R. Vold for a NSF postdoctoral appointment under grant CHE 81-22097 and Dr. John Wright for technical assistance.

PY - 1985

Y1 - 1985

N2 - The14N quadrupole coupling constant (QCC) for methyl isocyanide obtained from 1H and 14N N.M.R. measurements in liquid crystal solutions is reported as a function of temperature for two liquid crystal solvents. A marked linear temperature dependence is observed in both solvents. The measured QCC varies by 20 per cent over a 50°C range.

AB - The14N quadrupole coupling constant (QCC) for methyl isocyanide obtained from 1H and 14N N.M.R. measurements in liquid crystal solutions is reported as a function of temperature for two liquid crystal solvents. A marked linear temperature dependence is observed in both solvents. The measured QCC varies by 20 per cent over a 50°C range.

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DO - 10.1080/00268978500100501

M3 - Article

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EP - 656

JO - Molecular Physics

JF - Molecular Physics

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ER -

Anomalous ¹⁴N quadrupole coupling constant of methyl isocyanide in liquid crystals

Abstract

ASJC Scopus subject areas

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