Anomalous 14N quadrupole coupling constant of methyl isocyanide in liquid crystals

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Abstract

The14N quadrupole coupling constant (QCC) for methyl isocyanide obtained from 1H and 14N N.M.R. measurements in liquid crystal solutions is reported as a function of temperature for two liquid crystal solvents. A marked linear temperature dependence is observed in both solvents. The measured QCC varies by 20 per cent over a 50°C range.

Original languageEnglish (US)
Pages (from-to)651-656
Number of pages6
JournalMolecular Physics
Volume54
Issue number3
DOIs
StatePublished - Jan 1 1985

ASJC Scopus subject areas

  • Biophysics
  • Molecular Biology
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry

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