An improved and versatile synthetic route to 6,7

13,14-dibenzo-1,8,4,11-dioxadiazacyclotetradecane

Mark Woods, A. Dean Sherry

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

A new and effective synthetic pathway to 6,7:13,14-dibenzo-1,8,4,11-dioxadiazacyclotetradecane (1) has been developed. Beginning from salicylic acid, this synthetic pathway involves five high yielding steps to afford the macrocycle 6,7:13,14-dibenzo-1,8,4,11-dioxadiazacyclotetradecane-3,10-dione. Reduction of this macrocycle afforded the dioxadiaza crown 1 with an overall yield of 60%.

Original languageEnglish (US)
Pages (from-to)395-398
Number of pages4
JournalInorganica Chimica Acta
Volume351
Issue number1
DOIs
StatePublished - Jul 22 2003
Externally publishedYes

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Salicylic acid
Salicylic Acid
Dione
Crowns
routes
acids

Keywords

  • Azaoxacrownethers
  • Macrocyclic synthesis

ASJC Scopus subject areas

  • Biochemistry
  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

An improved and versatile synthetic route to 6,7 : 13,14-dibenzo-1,8,4,11-dioxadiazacyclotetradecane. / Woods, Mark; Sherry, A. Dean.

In: Inorganica Chimica Acta, Vol. 351, No. 1, 22.07.2003, p. 395-398.

Research output: Contribution to journalArticle

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