An efficient and selective method for hydrolysis of acetonides

X. Xiao; D. Bai

doi:10.1055/s-2001-12340

An efficient and selective method for hydrolysis of acetonides

X. Xiao, D. Bai

Research output: Contribution to journal › Article › peer-review

52 Scopus citations

Abstract

Acetonide was selectively and efficiently cleaved with cerium (III) chloride heptahydrate and oxalic acid in acetonitrile. This method was found to be of good functionalities compatibility with such acid sensitive groups as Tr, PMB, TBDMS, TBDPS, OAc, OBz, OTs, OTf.

Original language	English (US)
Pages (from-to)	535-537
Number of pages	3
Journal	Synlett
Issue number	4
DOIs	https://doi.org/10.1055/s-2001-12340
State	Published - 2001
Externally published	Yes

Keywords

Acetonides
Cerium (III) chloride
Diols
Oxalic acid

ASJC Scopus subject areas

Organic Chemistry

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10.1055/s-2001-12340

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title = "An efficient and selective method for hydrolysis of acetonides",

abstract = "Acetonide was selectively and efficiently cleaved with cerium (III) chloride heptahydrate and oxalic acid in acetonitrile. This method was found to be of good functionalities compatibility with such acid sensitive groups as Tr, PMB, TBDMS, TBDPS, OAc, OBz, OTs, OTf.",

keywords = "Acetonides, Cerium (III) chloride, Diols, Oxalic acid",

author = "X. Xiao and D. Bai",

year = "2001",

doi = "10.1055/s-2001-12340",

language = "English (US)",

pages = "535--537",

journal = "Synlett",

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T1 - An efficient and selective method for hydrolysis of acetonides

AU - Xiao, X.

AU - Bai, D.

PY - 2001

Y1 - 2001

N2 - Acetonide was selectively and efficiently cleaved with cerium (III) chloride heptahydrate and oxalic acid in acetonitrile. This method was found to be of good functionalities compatibility with such acid sensitive groups as Tr, PMB, TBDMS, TBDPS, OAc, OBz, OTs, OTf.

AB - Acetonide was selectively and efficiently cleaved with cerium (III) chloride heptahydrate and oxalic acid in acetonitrile. This method was found to be of good functionalities compatibility with such acid sensitive groups as Tr, PMB, TBDMS, TBDPS, OAc, OBz, OTs, OTf.

KW - Acetonides

KW - Cerium (III) chloride

KW - Diols

KW - Oxalic acid

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U2 - 10.1055/s-2001-12340

DO - 10.1055/s-2001-12340

M3 - Article

AN - SCOPUS:0035070802

SN - 0936-5214

SP - 535

EP - 537

JO - Synlett

JF - Synlett

IS - 4

ER -

An efficient and selective method for hydrolysis of acetonides

Abstract

Keywords

ASJC Scopus subject areas

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