@article{af1abc814edf4d83b287237832e1431f,
title = "A Nonheme Sulfur-Ligated {FeNO}6 Complex and Comparison with Redox-Interconvertible {FeNO}7 and {FeNO}8 Analogues",
abstract = "A nonheme {FeNO}6 complex, [Fe(NO)(N3PyS)]2+, was synthesized by reversible, one-electron oxidation of an {FeNO}7 analogue. This complex completes the first known series of sulfur-ligated {FeNO}6–8 complexes. All three {FeNO}6–8 complexes are readily interconverted by one-electron oxidation/reduction. A comparison of spectroscopic data (UV/Vis, NMR, IR, M{\"o}ssbauer, X-ray absorption) provides a complete picture of the electronic and structural changes that occur upon {FeNO}6–{FeNO}8 interconversion. Dissociation of NO from the new {FeNO}6 complex is shown to be controlled by solvent, temperature, and photolysis, which is rare for a sulfur-ligated {FeNO}6 species.",
keywords = "iron, nitrosyl ligands, nonheme complexes, photolysis, sulfur",
author = "Aniruddha Dey and Confer, {Alex M.} and Vilbert, {Avery C.} and Pierre Mo{\"e}nne-Loccoz and Lancaster, {Kyle M.} and Goldberg, {David P.}",
note = "Funding Information: The NSF (CHE1566007 to D.P.G.) and NIH (GM074785 to P.M.L. and GM124908 to K.M.L.) are gratefully acknowledged for financial support. A.M.C. thanks the Harry and Cleio Greer Fellowship for support. XAS data were obtained at SSRL, supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under Contract No. DE-AC02-76SF00515. The SSRL Structural Molecular Biology Program is supported by the Office of Biological and Environmental Research of the Department of Energy, and by NIH/NIGMS (including P41GM103393). Publisher Copyright: {\textcopyright} 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim",
year = "2018",
month = oct,
day = "8",
doi = "10.1002/anie.201806146",
language = "English (US)",
volume = "57",
pages = "13465--13469",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
publisher = "John Wiley and Sons Ltd",
number = "41",
}