A Nonheme Sulfur-Ligated {FeNO}6 Complex and Comparison with Redox-Interconvertible {FeNO}7 and {FeNO}8 Analogues

Aniruddha Dey, Alex M. Confer, Avery C. Vilbert, Pierre Moenne-Loccoz, Kyle M. Lancaster, David P. Goldberg

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

A nonheme {FeNO}6 complex, [Fe(NO)(N3PyS)]2+, was synthesized by reversible, one-electron oxidation of an {FeNO}7 analogue. This complex completes the first known series of sulfur-ligated {FeNO}6–8 complexes. All three {FeNO}6–8 complexes are readily interconverted by one-electron oxidation/reduction. A comparison of spectroscopic data (UV/Vis, NMR, IR, Mössbauer, X-ray absorption) provides a complete picture of the electronic and structural changes that occur upon {FeNO}6–{FeNO}8 interconversion. Dissociation of NO from the new {FeNO}6 complex is shown to be controlled by solvent, temperature, and photolysis, which is rare for a sulfur-ligated {FeNO}6 species.

Original languageEnglish (US)
Pages (from-to)13465-13469
Number of pages5
JournalAngewandte Chemie - International Edition
Volume57
Issue number41
DOIs
StatePublished - Oct 8 2018

Fingerprint

Sulfur
Electrons
Photolysis
X ray absorption
Nuclear magnetic resonance
Oxidation
Temperature
Oxidation-Reduction

Keywords

  • iron
  • nitrosyl ligands
  • nonheme complexes
  • photolysis
  • sulfur

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

Cite this

A Nonheme Sulfur-Ligated {FeNO}6 Complex and Comparison with Redox-Interconvertible {FeNO}7 and {FeNO}8 Analogues. / Dey, Aniruddha; Confer, Alex M.; Vilbert, Avery C.; Moenne-Loccoz, Pierre; Lancaster, Kyle M.; Goldberg, David P.

In: Angewandte Chemie - International Edition, Vol. 57, No. 41, 08.10.2018, p. 13465-13469.

Research output: Contribution to journalArticle

Dey, Aniruddha ; Confer, Alex M. ; Vilbert, Avery C. ; Moenne-Loccoz, Pierre ; Lancaster, Kyle M. ; Goldberg, David P. / A Nonheme Sulfur-Ligated {FeNO}6 Complex and Comparison with Redox-Interconvertible {FeNO}7 and {FeNO}8 Analogues. In: Angewandte Chemie - International Edition. 2018 ; Vol. 57, No. 41. pp. 13465-13469.
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