2H NMR lineshapes in deuterium molybdenum bronze 2H1.66MoO3

Thomas Barbara, S. Sinha, J. Jonas, D. Tinet, J. J. Fripiat

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

2H NMR lineshapes for the deuterium molybdenum bronze H1.66MoO3 were measured over the temperature range 20-410 K using the quadrupolar echo technique. The low temperature lineshape demonstrates the existence of two equally populated deuterium sites in the lattice. At 200 K, a motionally narrowed, completely asymmetric pattern is observed. The width is substantially less than that expected for simple flips of OH2 moieties or quasi one-dimensional motion.

Original languageEnglish (US)
Pages (from-to)669-673
Number of pages5
JournalJournal of Physics and Chemistry of Solids
Volume47
Issue number7
DOIs
StatePublished - 1986
Externally publishedYes

Fingerprint

Molybdenum
Deuterium
Bronze
bronzes
molybdenum
deuterium
Nuclear magnetic resonance
nuclear magnetic resonance
echoes
Temperature
temperature

Keywords

  • Deuterium
  • hydrogen molybdenum bronze
  • NMR lineshapes

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics

Cite this

2H NMR lineshapes in deuterium molybdenum bronze 2H1.66MoO3. / Barbara, Thomas; Sinha, S.; Jonas, J.; Tinet, D.; Fripiat, J. J.

In: Journal of Physics and Chemistry of Solids, Vol. 47, No. 7, 1986, p. 669-673.

Research output: Contribution to journalArticle

Barbara, Thomas ; Sinha, S. ; Jonas, J. ; Tinet, D. ; Fripiat, J. J. / 2H NMR lineshapes in deuterium molybdenum bronze 2H1.66MoO3. In: Journal of Physics and Chemistry of Solids. 1986 ; Vol. 47, No. 7. pp. 669-673.
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